Versatile synthesis of chiral 6-oxoverdazyl radical ligands – new building blocks for multifunctional molecule-based magnets
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چکیده
منابع مشابه
[Synthesis and its application to the synthesis of biologically active natural products of new and versatile chiral building blocks].
This article describes a design and synthesis of new and versatile chiral building blocks and its application to the biologically active natural product synthesis. The chiral building blocks were prepared using a biocatalysis in an enantiomerically pure state. As an application of the above chiral building blocks to the synthesis of biologically active natural product, we demonstrated the diast...
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In the past decade there has been a significant growth in the sales of pharmaceutical drugs worldwide, but more importantly there has been a dramatic growth in the sales of single enantiomer drugs. The pharmaceutical industry has a rising demand for chiral intermediates and research reagents because of the continuing imperative to improve drug efficacy. This in turn impacts on researchers invol...
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This thesis presents a selection of the scientific activity gained by the candidate over the course of the last 14 years, including exclusively scientific results obtained after the public defence of her PhD thesis, as well as the brief description of some maine future research directions. The abilitation thesis contains 5 chapters. After the first introduction chapter, in the second (Enantioto...
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Neste trabalho, descrevemos a obtenção de dois novos compostos de cobre(II), ou precursores, (Pr-Rad) 2 [Cu(opba)].H 2 O (1) e (Bu-Rad) 2 [Cu(opba)].2H 2 O (2), onde opba é o ligante ortofenilenobis(oxamato) e R-Rad são radicais cátions do tipo nitronil nitróxido. A partir destes compostos 1 e 2, foram sintetizados os dois novos magnetos moleculares [Pr-Rad] 2 [Mn 2 {Cu(opba)} 3 ].3,3 DMSO.5H 2...
متن کاملMultifunctional "clickates" as versatile extended heteroaromatic building blocks: efficient synthesis via click chemistry, conformational preferences, and metal coordination.
Click chemistry has been utilized to access 2,6-bis(1-aryl-1,2,3-triazol-4-yl)pyridines (BTPs) as versatile extended heteroaromatic building blocks for their exploitation in supramolecular chemistry, in particular foldamer and ligand design. In addition to their high-yielding synthesis using Cu(I)-catalyzed Huisgen-type 1,3-dipolar cycloaddition reactions the formed triazole moieties constitute...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2018
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c8dt00840j